Preheat oven to 350℉. Spray a 9x13 pan with non-stick cooking spray and set aside.
In a large bowl or bowl of a stand mixer with a paddle attachment, add flour, sugar, cocoa, baking powder, baking soda, and salt. Whisk to combine.
2 cups all-purpose flour, 1½ cups granulated sugar, ¾ cup dutch-processed cocoa powder, 2 tsp baking powder, 1½ tsp baking soda, 1 tsp salt
In a separate bowl, whisk together the buttermilk, oil, eggs, and vanilla. Pour this into the dry ingredients and mix until combined.
1 cup buttermilk, ½ cup vegetable oil, 2 large eggs, 2 tsp vanilla extract
Carefully add in hot water and mix until fully combined.
1 cup hot water
Pour into the greased pan and bake for 30-35 minutes, or until the top is set and a toothpick inserted into the middle of the cake comes out clean or few crumbs.
Allow the cake to cool completely on a wire cooling rack.